Volume 8 Issue 2
Apr.  2023
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Article Navigation >  Green Energy&Environment  > 2023  >  8(2): 499-508
Ping Wang, Xiaoling Mou, Yong Li, Wenjie Shen. Green rusts-derived iron oxide nanostructures catalyze NO reduction by CO. Green Energy&Environment, 2023, 8(2): 499-508. doi: 10.1016/j.gee.2021.06.002
Citation: Ping Wang, Xiaoling Mou, Yong Li, Wenjie Shen. Green rusts-derived iron oxide nanostructures catalyze NO reduction by CO. Green Energy&Environment, 2023, 8(2): 499-508. doi: 10.1016/j.gee.2021.06.002
shu

Green rusts-derived iron oxide nanostructures catalyze NO reduction by CO

doi: 10.1016/j.gee.2021.06.002

  • a. Hangzhou Institute of Advanced Studies, Zhejiang Normal University, Hangzhou, 311231, China;

  • b. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China

Funds:

We thank Zhejiang Normal University for providing the financial support (YS304320035). Profs. Y. Cui and C. Yang are thanked for their help with the XPS measurement and FTIR analysis, respectively.

  • Received date 28 March 2021, Accepted date 27 June 2021, RevRecd date 23 June 2021, Publish date 29 June 2021,
    Abstract
  • Green rusts with brucite-like layers of hydroxide intercalated with anions constitute a family of diverse precursors for the synthesis of iron oxides via dehydration, but precise structural control of the resulting oxides with respect to the size and shape at the nanometer level remains challenging due to the easy oxidation of the ferrous species. Herein, we report a new synthetic strategy for the facile preparation of fibrous-like green rusts by using appropriate balancing anions (CO32- and SO42-) in ethylene glycol to regulate the morphology. Depending on the type of the intercalating anion, the green rusts were converted into hematite with fibrous-or plate-like shapes upon thermal activation. When evaluated in the reaction of NO reduction by CO, these iron oxides showed a prominent shape-dependent catalytic behavior. The fibrous-like Fe2O3 was much more catalytically active and structurally robust than the plate-like analogue. Combined spectroscopic and microscopic characterizations on the nanostructured iron oxides revealed that the superior performance of the fibrous-like Fe2O3 stemmed from a facile Fe2O3/Fe3O4 redox cycle and a higher density of active sites for NO activation.

     

    • • Fibrous-like green rusts with different structures synthesized in ethylene glycol. • Hematites with fibrous- and plate-like morphologies obtained from green rusts. • Prominent morphology effect of hematites evidenced in catalyzed NO reduction with CO. • Structure–activity relationships established.
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