Volume 8 Issue 2
Apr.  2023
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Article Navigation >  Green Energy&Environment  > 2023  >  8(2): 478-486
Yawen Fu, Yanan Xu, Zepeng Zeng, Abdul-Rauf Ibrahim, Jin Yang, Shuliang Yang, Yaqiang Xie, Yanzhen Hong, Yuzhong Su, Hongtao Wang, Yanliang Wang, Li Peng, Jun Li, Wendy L. Queen. Mesoporous poly(ionic liquid)s with dual active sites for highly efficient CO2 conversion. Green Energy&Environment, 2023, 8(2): 478-486. doi: 10.1016/j.gee.2021.05.013
Citation: Yawen Fu, Yanan Xu, Zepeng Zeng, Abdul-Rauf Ibrahim, Jin Yang, Shuliang Yang, Yaqiang Xie, Yanzhen Hong, Yuzhong Su, Hongtao Wang, Yanliang Wang, Li Peng, Jun Li, Wendy L. Queen. Mesoporous poly(ionic liquid)s with dual active sites for highly efficient CO2 conversion. Green Energy&Environment, 2023, 8(2): 478-486. doi: 10.1016/j.gee.2021.05.013
shu

Mesoporous poly(ionic liquid)s with dual active sites for highly efficient CO2 conversion

doi: 10.1016/j.gee.2021.05.013

  • a. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China;

  • b. Mechanical Engineering Department, Tamale Technical University, Tamale, Ghana;

  • c. College of Energy, Xiamen University, Xiamen, 361102, China;

  • d. National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, Xiamen University, Xiamen, 361005, China;

  • e. Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen, 361005, China;

  • f. Institute of Chemical Sciences and Engineering, École Polytechnique Fédérale de Lausanne (EPFL), EPFL-ISIC-Valais, Sion, Switzerland

Funds:

The authors acknowledge financial support from the National Natural Science Foundation of China (22078274, 21903066).

  • Received date 02 March 2021, Accepted date 28 May 2021, RevRecd date 18 May 2021, Publish date 04 June 2021,
    Abstract
  • Atmospheric CO2 concentrations are soaring due to the continued use of fossil fuels in energy production, an anthropogenic activity that is playing a leading role in global warming. Thus, research aimed at the capture and conversion of CO2 into value-added products, such as cyclic carbonates, is booming. While CO2 is an abundant, cheap, non-toxic, and readily accessible C1 feedstock, its thermodynamic stability necessitates the development of highly efficient catalysts that are able to promote chemical reactions under mild conditions. In this work, a novel mesoporous poly(ionic liquid) with dual active sites was synthesized through a facile method that involves co-polymerization, post-synthetic metalation, and supercritical CO2 drying. Due to a high density of nucleophilic and electrophilic sites, the as-prepared poly(ionic liquid), denoted as P2D-4BrBQA-Zn , offers excellent performance in a CO2 cycloaddition reaction using epichlorohydrin as the substrate (98.9% conversion and 96.9% selectivity). Moreover the reaction is carried out under mild, solvent-free, and additive-free conditions. Notably, P2D-4BrBQA-Zn also efficiently promotes the conversion of various other epoxide substrates into cyclic carbonates. Overall, the catalyst is found to have excellent substrate compatibility, stability, and recyclability.

     

    • • It is the first time to introduce the metal salt into quaternary ammonium-based MPILs with high ionic density. • P2D-4BrBQA-Zn showed high CO2 adsorption capacity and yield of cyclic carbonates for broad epoxides under mild conditions. • The as-prepared catalyst could be easily separated and showed good stability during the reaction. • The strategy of constructing dual active sites could be used to expand the applications of PILs in the future.
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