Volume 8 Issue 1
Feb.  2023
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Article Navigation >  Green Energy&Environment  > 2023  >  8(1): 173-182
Qiuzhun Chen, Dong Wang, Chuan Gao, Bin Wang, Shengli Niu, Gaiju Zhao, Yue Peng, Junhua Li, Chunmei Lu, John Crittenden. Cerium-tungsten oxides supported on activated red mud for the selective catalytic reduction of NOx. Green Energy&Environment, 2023, 8(1): 173-182. doi: 10.1016/j.gee.2021.03.008
Citation: Qiuzhun Chen, Dong Wang, Chuan Gao, Bin Wang, Shengli Niu, Gaiju Zhao, Yue Peng, Junhua Li, Chunmei Lu, John Crittenden. Cerium-tungsten oxides supported on activated red mud for the selective catalytic reduction of NOx. Green Energy&Environment, 2023, 8(1): 173-182. doi: 10.1016/j.gee.2021.03.008
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Cerium-tungsten oxides supported on activated red mud for the selective catalytic reduction of NOx

doi: 10.1016/j.gee.2021.03.008

  • a. National Engineering Laboratory for Coal-Burning Pollutants Emission Reduction, School of Energy and Power Engineering, Shandong University, Jinan, 250061, China;

  • b. State Key Joint Laboratory of Environment Simulation and Pollution Control, National Engineering Laboratory for Multi Flue Gas Pollution Control Technology and Equipment, School of Environment, Tsinghua University, Beijing, 100084, China;

  • c. Brook Byers Institute for Sustainable Systems and School of Civil and Environmental Engineering, Georgia Institute of Technology, 828 West Peachtree Street, Atlanta, GA, 30332, United States;

  • d. Energy Institute, Qilu University of Technology(Shandong Academy of Sciences), Jinan, 250013, Shandong, China

Funds:

Development Project of Shandong Province (2018GSF117034, 2019JZZY020305).

This work was financially supported by the National Natural Science Foundation of China (21906090), the National Key Research and Development Program (2017YFC0210200, 2017YFC0212800), and Primary Research &

  • Received date 07 January 2021, Accepted date 14 March 2021, RevRecd date 09 March 2021, Publish date 17 March 2021,
    Abstract
  • Activated red mud (RM) has been proved to be a promising base material for the selective catalysis reduction (SCR) of NOx. The inherent low reducibility and acidity limited its low-temperature activity. In this work, molybdenum oxide, tungsten oxide, and cerium oxide were used to reconfigure the redox sites and acid sites of red mud based catalyst. When activated red mud was reconfigured by cerium-tungsten oxide (Ce-W@RM), the NOx conversion kept above 90% at 219-480 ℃. The existence of Ce3+/Ce4+ redox electron pairs provided more surface adsorbed oxygen (Oα) and served as a redox cycle. Positive interactions between Ce, W species and Fe oxide in red mud occurred, which led to the formation of unsaturated chemical bond and promoted the activation of adsorbed NH3 species. WO3 and Ce2(WO4)3 (formed by solid-state reaction between Ce and W species) could provide more Brønsted acid sites (W-O modes of WO3, WO or W-O-W modes of Ce2(WO4)3). CeO2 species could provide more Lewis acid sites. The Langmuir-Hinshelwood (L-H) routes and Eley-Rideal (E-R) routes occurred in the low-temperature SCR reaction on the Ce-W@RM surface. NH4+ species on Brønsted acid sites, NH3 species on Lewis acid sites, bidentate nitrate and bridging nitrate species were key active intermediates species.

     

    • • Cerium-tungsten oxides could reconfigure the redox sites and acid sites of red mud based catalyst. • Cerium-tungsten supported red mud based catalyst kept above 90% NO conversion at 219–480 °C. • Abundant Ce3+ and unsaturated chemical bond improved the redox properties of catalyst. • Ce2(WO4)3 formed by solid–state reaction between Ce and W species promoted NH3 adsorption.
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