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Article Navigation >  Green Energy&Environment  > 2017  >  2(2): 124-133
Zhigang Chen, Jie Zeng, Jun Di, Dexiang Zhao, Mengxia Ji, Jiexiang Xia, Huaming Li. Facile microwave-assisted ionic liquid synthesis of sphere-like BiOBr hollow and porous nanostructures with enhanced photocatalytic performance. Green Energy&Environment, 2017, 2(2): 124-133. doi: 10.1016/j.gee.2017.01.005
Citation: Zhigang Chen, Jie Zeng, Jun Di, Dexiang Zhao, Mengxia Ji, Jiexiang Xia, Huaming Li. Facile microwave-assisted ionic liquid synthesis of sphere-like BiOBr hollow and porous nanostructures with enhanced photocatalytic performance. Green Energy&Environment, 2017, 2(2): 124-133. doi: 10.1016/j.gee.2017.01.005
shu

Facile microwave-assisted ionic liquid synthesis of sphere-like BiOBr hollow and porous nanostructures with enhanced photocatalytic performance

doi: 10.1016/j.gee.2017.01.005
  • a.

    School of Environment and Safety Engineering, Ministry of Education, Jiangsu University, Zhenjiang 212013, China

  • b.

    School of Chemistry and Chemical Engineering, Ministry of Education, Jiangsu University, Zhenjiang 212013, China

  • c.

    Key Laboratory of Modern Agriculture Equipment and Technology, Ministry of Education, Jiangsu University, Zhenjiang 212013, China

More Information
  • Corresponding author: E-mail address: chenzg01@126.com (Zhigang Chen); E-mail address: xjx@ujs.edu.cn (Jiexiang Xia); E-mail address: lhm@ujs.edu.cn (Huaming Li)
  • Received date 28 November 2016, Accepted date 22 January 2017, RevRecd date 20 January 2017, Available online 06 February 2017, Publish date 30 April 2017,
    Abstract
  • In this work, two kinds of self-assembled hierarchical BiOBr microcrystals were rapidly synthesized through a simple microwave-assisted route in the presence of reactable ionic liquid 1-hexadecyl-3-methylimidazolium bromide ([C16mim]Br). These porous and hollow BiOBr microspheres were obtained via a facile solvothermal method with or without polyvinyl pyrrolidone (PVP), respectively. During the synthetic process, ionic liquid [C16mim]Br played as solvent, reactant and template at the same time. Moreover, the BiOBr hollow and porous microspheres exhibited outstanding photocatalytic activities for the degradation of rhodamine B (RhB) under visible light irradiation. A possible photocatalytic mechanism was also discussed in detail. It can be assumed that the higher photocatalytic activities of BiOBr porous microspheres materials could be ascribed to the novel structure, larger specific surface area, narrower band gap structure and smaller particle size.

     

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