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Article Navigation >  Green Energy&Environment  > 2017  >  2(2): 112-118
Haoxuan Zhang, Haibo Jiang, Yanjie Hu, Hao Jiang, Chunzhong Li. Integrated Ni-P-S nanosheets array as superior electrocatalysts for hydrogen generation. Green Energy&Environment, 2017, 2(2): 112-118. doi: 10.1016/j.gee.2016.12.004
Citation: Haoxuan Zhang, Haibo Jiang, Yanjie Hu, Hao Jiang, Chunzhong Li. Integrated Ni-P-S nanosheets array as superior electrocatalysts for hydrogen generation. Green Energy&Environment, 2017, 2(2): 112-118. doi: 10.1016/j.gee.2016.12.004
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Integrated Ni-P-S nanosheets array as superior electrocatalysts for hydrogen generation

doi: 10.1016/j.gee.2016.12.004

  • Key Laboratory for Ultrafine Materials of Ministry of Education & School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China

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  • Corresponding author: E-mail address: jianghao@ecust.edu.cn (Hao Jiang); E-mail address: czli@ecust.edu.cn (Chunzhong Li)
  • Received date 23 November 2016, Accepted date 27 December 2016, RevRecd date 22 December 2016, Available online 04 January 2017, Publish date 30 April 2017,
    Abstract
  • Searching for efficient and robust non-noble electrocatalysts for hydrogen generation is extremely desirable for future green energy systems. Here, we present the synthesis of integrated Ni-P-S nanosheets array including Ni2P and NiS on nickel foam by a simple simultaneous phosphorization and sulfurization strategy. The resultant sample with optimal composition exhibits superior electrocatalytic performance for hydrogen evolution reaction (HER) in a wide pH range. In alkaline media, it can generate current densities of 10, 20 and 100 mA cm−2 at low overpotentials of only −101.9, −142.0 and −207.8 mV with robust durability. It still exhibits high electrocatalytic activities even in acid or neutral media. Such superior electrocatalytic performances can be mainly attributed to the synergistic enhancement of the hybrid Ni-P-S nanosheets array with integration microstructure. The kind of catalyst gives a new insight on achieving efficient and robust hydrogen generation.

     

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